3,402 research outputs found

    Revisiting transitional metaphors: reproducing inequalities under the conditions of late modernity

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    This paper focuses on some of the conceptual implications changes in youth transitions over the last 40 years. I argue that changes have often been exaggerated with researchers too enthusiastic to jump on theoretical bandwagons without due regard for empirical evidence. While I suggest that there are important changes that impact on the ways in which social classes are reproduced, involving a perception of increased opportunity and greater scope for individual agency, a degree of class-based convergence and illusions regarding the disappearance of class, I will argue that the new mechanisms lead to the re-establishment of very familiar patterns of socio-economic inequality which can largely be understood by employing established theoretical ideas. While biographical approaches are regarded as useful, the continued use of social class is defended

    Introduction: The history and scope of the sociology of higher education

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    Streamlining Sound Speed Profile Pre-Processing: Case Studies and Field Trials

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    High rate sound speed profiling systems have the potential to maximize the efficiency of multibeam echosounder systems (MBES) by increasing the accuracy at the outer edges of the swath where refraction effects are at their worst. In some cases, high rate sampling on the order of tens of casts per hour is required to capture the spatio-temporal oceanographic variability and this increased sampling rate can challenge the data acquisition workflow if refraction corrections are to be applied in real-time. Common bottlenecks result from sound speed profile (SSP) preprocessing requirements, e.g. file format conversion, cast extension, reduction of the number of points in the cast, filtering, etc. Without the ability to quickly pre-process SSP data, the MBES operator can quickly become overwhelmed with SSP related tasks, potentially to the detriment of their other duties. A series of algorithms are proposed in which SSPs are automatically pre-processed to meet input criteria of MBES acquisition systems, specifically the problems of cast extrapolation and thinning are addressed. The algorithmic performance will be assessed in terms of sounding uncertainty through a series of case studies in a variety of oceanographic conditions and water depths. Results from a field trial in the French Mediterranean will be used to assess the improvement in real-time MBES acquisition workflow and survey accuracy and will also highlight where further improvements can be made in the pre-processing pipeline

    Design and Control of a Flight-Style AUV with Hovering Capability

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    The small flight-style Delphin AUV is designed to evaluate the performance of a long range survey AUV with the additional capability to hover and manoeuvre at slow speed. Delphin’s hull form is based on a scaled version of Autosub6000, and in addition to the main thruster and control surfaces at the rear of the vehicle, Delphin is equipped with four rim driven tunnel thrusters. In order to reduce the development cycle time, Delphin was designed to use commercial-off-the-shelf (COTS) sensors and thrusters interfaced to a standard PC motherboard running the control software within the MS Windows environment. To further simplify the development, the autonomy system uses the State-Flow Toolbox within the Matlab/Simulink environment. While the autonomy software is running, image processing routines are used for obstacle avoidance and target tracking, within the commercial Scorpion Vision software. This runs as a parallel thread and passes results to Matlab via the TCP/IP communication protocol. The COTS based development approach has proved effective. However, a powerful PC is required to effectively run Matlab and Simulink, and, due to the nature of the Windows environment, it is impossible to run the control in hard real-time. The autonomy system will be recoded to run under the Matlab Windows Real-Time Windows Target in the near future. Experimental results are used to demonstrating the performance and current capabilities of the vehicle are presented

    Tautomeric Equilibria Studies by Mass Spectrometry

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    Tautomerism in organic chemistry has been extensively studied in condensed phase by spectrometric methods, mainly by IR and NMR techniques. Mass spectrometry studies start 40 years ago but just recently it has been recognized the importance of the mass spectral data for the study of tautomerism in the gas phase.
Mass spectrometry can provide valuable information in regard to tautomeric equilibria when studying mass spectra among the members of different families of organic compounds.
The relevance of the mass spectral data resides on several facts but there are two that are of key importance:
1-	Mass spectral fragmentation assignments should be tautomer specific since the corresponding abundances ratios are supposed to be correlated to the keto/enol contents.
2-	Ionization in the ion source is supposed to have no effect on the position of the equilibrium so that the results reflect the tautomers content in the gas phase previous to ionization.
Some of the carbonylic compounds do not exhibit noticeable tautomerism so the fragment abundances assigned to the enol form is very low or not measurable. Since enolization is more noticeable in the case of thio-derivatives (which correlates adequately with the oxygenated analogues), the study of their mass spectra is an interesting choice to reach some degree of generalization. 
In addition, experimental findings are supported by semiempirical theoretical calculations, which probed to be adequate not only for supporting tendency correlations among the members of a compound family but also to calculate heats of tautomerization in gas phase.
Reports using mass spectrometry for tautomerism are becoming less common. One of the reasons is that now it would appear that the interpretation of MS results is not as straightforward as it was once believed, even though in a recent review it was written that: “Mass spectrometry is the most informative and practical method for studying and identifying tautomers in the gas phase” [1]. 
In fact, mass spectrometry seems to be very informative for studying and identifying tautomers, because in this case external factors like solvents, intermolecular interactions, etc., can be excluded by transferring the tautomeric system into gas phase, where the process becomes truly unimolecular [1].
This review covers the study of Tautomerism by Mass Spectrometry in the last four decades. 
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    Introduction: The history and scope of the sociology of higher education

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    No abstract available

    ACUTE EFFECTS OF WHOLE-BODY VIBRATION ON ELASTIC CHARGE TIME IN TRAINED MALE ATHLETES

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    Whole-body vibration (WBV) has been shown to increase jump height, power and strength but the mechanisms behind these changes are not fully understood. The aim of this study was to investigate the influence of WBV on elastic charge time, a surrogate measure of tendon and aponeurosis stiffness. 7 trained males were exposed to 10 vibrations at 30 Hz ± 4 mm with 60 seconds rest between each exposure. Pre and post-tests were conducted immediately, 5, 10, 15, 20, 30 and 40 minutes following vibration exposure. A significant increase in elastic charge times of both vibrated (p=0.004) and control (p=0.024) limbs suggest whole-body vibration decreases tendon and aponeurosis stiffness, possibly due to a warm-up effect of the lower limbs. Further study of the muscle stiffness response to vibration will improve understanding of the mechanisms behind performance improvements following vibration exposure

    Come On Down: Investigating an Informational Strategy to Debias the Anchoring Heuristic

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    When individuals estimate the price of goods or services, irrelevant factors may affect the estimates. For example, irrelevant numbers in individuals’ environments can cause participants to “anchor” to them as starting point price estimates, such that estimates tend toward the anchor (Tversky & Kahneman, 1974; Chapman & Johnson, 1994). In fact, anchored individuals may pay up to three times as much for a product and buy 32% more products (Ariely, Loewenstein, & Prelec, 2003; Wansink, Kent, & Hoch, 1998). Because anchoring affects purchases large and small, this study investigates how to debias, or reduce the negative effects of, the anchoring heuristic. Debiasing strategies are not easily implemented outside the lab where anchoring has the largest real world effects (Strack & Mussweiler, 1997; Chapman & Johnson, 1994; George, Duffy, & Ahuja, 2000). We therefore investigated an easily implemented informational debiasing strategy offering little disruption to an individual’s daily routine. The debiasing had no effect on anchoring, but further investigation with a larger sample size and higher external validity is necessary before discounting the strategy completely
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